Carbon-based Energy Carrier Research Team

Developing a Hydrogen Carrier System for CO2 Utilization

We are engaged in the research and development of energy (hydrogen) storage technologies based on interconversion between CO2 and formic acid/methanol, for CO2 utilization.We are developing innovative systems to store and upgrade thermal energy at high temperature utilizing chemical reaction between hydrogen and metals.

Carbon-based Energy Carrier Research Team

Research themes

  • Development of highly efficient catalysts that enable formic acid/methanol to be produced through carbon dioxide reduction (i.e., hydrogenation, electro-reduction), and that allow hydrogen to be produced from formic acid
  • Investigation into technologies for producing high-pressure hydrogen from formic acid
  • Development of thermochemical energy storage system and chemical heat pump utilizing reaction between hydrogen and metals

Concept for social contributions and implementation

Establishment of a hydrogen transport, storage and usage method using formic acid/methanol. Supply thermal energy without CO2 emission by using hydrogen as a thermal energy conversion/storage medium.

Members

Principal Research Manager (Leader, Carbon-based Energy Carrier Research Team)

ISHIDA Takao

Principal Researcher (Carbon-based Energy Carrier Research Team)

HIMEDA Yuichiro

Director, Research Planning Office of Energy and Environment (GZR Hydrogen Production and Storage Team)

TAKAGI Hideyuki

Senior Researcher

ONISHI Naoya

Member

SAKAKI Kouji

Member

ASANO Kohta

Member

SHINZATO Keita

Technical Staff

KOKUBO Masako

Technical Staff

HIROSE Kayoko

Technical Staff

MAEKAWA Hide

The aims in this team are development of highly efficient catalysts for interconversion between CO2 and formic acid/methanol (i.e., hydrogenation, electro-reduction, and dehydrogenation) and the high-pressure reaction process.

Production of Formic Acid and methanol by Reduction of CO2

The catalyst that we have developed showed the highest performance for CO2 reduction (hydrogenation, electro-reduction) to formic acid and methanol. These catalysts can convert CO2 with high energy efficiency under mild reaction conditions.

High-Pressure H2 Production from Formic Acid

The high-performance catalysts which can supply high-pressure (> 1000 atm) and CO-free H2 by heating (<100 oC) of formic acid was developed. In addition, gas-liquid phase separation can easily separate of CO2 from the high-pressure system. The high-pressure H2 production from formic acid is original AIST’s technology.

Thermal energy storage utilizing reaction between metals and hydrogen

Thermal energy storage system was developed by utilizing reversible reaction between metals and hydrogen. The system can store thermal energy at temperature higher than 600℃ and supply thermal energy to industries with less CO2 emission.

Research

Selected as the Journal Cover | Toward Methanol Production by CO2 Hydrogenation beyond Formic Acid Formation (ACS Publications)

Onishi, N.; Himeda, Y., Toward Methanol Production by CO2 Hydrogenation beyond Formic Acid Formation, Accounts Chem. Res. 2024, 57, 2816-2825

Published SEP 16 2024

Toda, H.; Kuroki, K.; Kanega, R.; Yano, T.; Yoshikawa, T.; Kuriyama, S.; Himeda, Y.; Sakata, K.; Nishibayasi, Y., Catalytic Ammonia Oxidation Using Ammonia Solution under Electrochemical Conditions: Investigation on Axial Ligand of Ruthenium Catalysts, Bull. Chem. Soc. Jpn. 2023, 96, 980-988

Published AUG 10 2023

Patra, S.; Maji, B.; Kawanami, H.; Himeda, Y., High-pressure hydrogen generation from dehydrogenation of formic acid, RSC Sustain. 2023, 1, 1655-1671

Published AUG 10 2023

Highlights

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